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  1. Abstract. Here we present a newly developed ice core gas-phase proxy that directlysamples a component of the large-scale atmospheric circulation:synoptic-scale pressure variability. Surface pressure changes weakly disrupt gravitational isotopic settling in the firn layer, which is recorded in krypton-86 excess (86Krxs). The 86Krxs may therefore reflect the time-averaged synoptic pressure variability over several years (site “storminess”), but it likely cannot record individual synoptic events as ice core gas samples typically average over several years. We validate 86Krxs using late Holocene ice samples from 11 Antarctic ice cores and 1 Greenland ice core that collectively represent a wide range of surface pressure variability in the modern climate. We find a strong spatial correlation (r=-0.94, p<0.01) between site average 86Krxs and time-averaged synoptic variability from reanalysis data. The main uncertainties in the analysis are the corrections for gas loss and thermal fractionation and the relatively large scatter in the data. Limited scientific understanding of the firn physics and potential biases of 86Krxs require caution in interpreting this proxy at present. We show that Antarctic 86Krxs appears to be linked to the position of the Southern Hemisphere eddy-driven subpolar jet (SPJ), with a southern position enhancing pressure variability. We present a 86Krxs record covering the last 24 kyr from the West Antarctic Ice Sheet (WAIS) Divide ice core. Based on the empirical spatial correlation of synoptic activity and 86Krxs at various Antarctic sites, we interpret this record to show that West Antarctic synoptic activity is slightly below modern levels during the Last Glacial Maximum (LGM), increases during the Heinrich Stadial 1 and Younger Dryas North Atlantic cold periods, weakens abruptly at the Holocene onset, remains low during the early and mid-Holocene, and gradually increases to its modern value. The WAIS Divide 86Krxs record resembles records of monsoon intensity thought to reflect changes in the meridional position of the Intertropical Convergence Zone (ITCZ) on orbital and millennial timescales such that West Antarctic storminess is weaker when the ITCZ is displaced northward and stronger when it is displaced southward. We interpret variations in synoptic activity as reflecting movement of the South Pacific SPJ in parallel to the ITCZ migrations, which is the expected zonal mean response of the eddy-driven jet in models and proxy data. Past changes to Pacific climate and the El Niño–Southern Oscillation (ENSO) may amplify the signal of the SPJ migration. Our interpretation is broadly consistent with opal flux records from the Pacific Antarctic zone thought to reflect wind-driven upwelling. We emphasize that 86Krxs is a new proxy, and more work is called for to confirm, replicate, and better understand these results; until such time, our conclusions regarding past atmospheric dynamics remainspeculative. Current scientific understanding of firn air transport andtrapping is insufficient to explain all the observed variations in86Krxs. A list of suggested future studies is provided. 
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  2. Abstract. A new ice core was drilled in West Antarctica on Skytrain Ice Rise in field season 2018/2019. This 651 m ice core is one of the main targets of the WACSWAIN (WArm Climate Stability of the West Antarctic ice sheet in the last INterglacial) project. A present-day accumulation rate of 13.5 cm w.e. yr−1 was derived. Although the project mainly aims to investigate the last interglacial (115–130 ka), a robust chronology period covering the recent past is needed to constrain the age models for the deepest ice. Additionally, this time period is important for understanding current climatic changes in the West Antarctic region. Here, we present a stratigraphic chronology for the top 184.14 m of the Skytrain ice core based on absolute age tie points interpolated using annual layer counting encompassing the last 2000 years of climate history. Together with a model-based depth–age relationship of the deeper part of the ice core, this will form the ST22 chronology. The chemical composition, dust content, liquid conductivity, water isotope concentration and methane content of the whole core was analysed via continuous flow analysis (CFA) at the British Antarctic Survey. Annual layer counting was performed by manual counting of seasonal variations in mainly the sodium and calcium records. This counted chronology was informed and anchored by absolute age tie points, namely, the tritium peak (1965 CE) and six volcanic eruptions. Methane concentration variations were used to further constrain the counting error. A minimal error of ±1 year at the tie points was derived, accumulating to ± 5 %–10 % of the age in the unconstrained sections between tie points. This level of accuracy enables data interpretation on at least decadal timescales and provides a solid base for the dating of deeper ice, which is the second part of the chronology. 
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  3. null (Ed.)
    Abstract. The last glacial period is characterized by a number of millennial climateevents that have been identified in both Greenland and Antarctic ice coresand that are abrupt in Greenland climate records. The mechanisms governingthis climate variability remain a puzzle that requires a precisesynchronization of ice cores from the two hemispheres to be resolved.Previously, Greenland and Antarctic ice cores have been synchronizedprimarily via their common records of gas concentrations or isotopes fromthe trapped air and via cosmogenic isotopes measured on the ice. In thiswork, we apply ice core volcanic proxies and annual layer counting toidentify large volcanic eruptions that have left a signature in bothGreenland and Antarctica. Generally, no tephra is associated with thoseeruptions in the ice cores, so the source of the eruptions cannot beidentified. Instead, we identify and match sequences of volcanic eruptionswith bipolar distribution of sulfate, i.e. unique patterns of volcanicevents separated by the same number of years at the two poles. Using thisapproach, we pinpoint 82 large bipolar volcanic eruptions throughout thesecond half of the last glacial period (12–60 ka). Thisimproved ice core synchronization is applied to determine the bipolarphasing of abrupt climate change events at decadal-scale precision. Inresponse to Greenland abrupt climatic transitions, we find a response in theAntarctic water isotope signals (δ18O and deuterium excess)that is both more immediate and more abrupt than that found with previousgas-based interpolar synchronizations, providing additional support for ourvolcanic framework. On average, the Antarctic bipolar seesaw climateresponse lags the midpoint of Greenland abrupt δ18O transitionsby 122±24 years. The time difference between Antarctic signals indeuterium excess and δ18O, which likewise informs the timeneeded to propagate the signal as described by the theory of the bipolarseesaw but is less sensitive to synchronization errors, suggests anAntarctic δ18O lag behind Greenland of 152±37 years.These estimates are shorter than the 200 years suggested by earliergas-based synchronizations. As before, we find variations in the timing andduration between the response at different sites and for different eventssuggesting an interaction of oceanic and atmospheric teleconnection patternsas well as internal climate variability. 
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